In chillers, hydrocarbons and ammonia are safe and energy-efficient alternatives to HFCs, both under moderate and high ambient temperature conditions. Heat pumps are also used with hydrocarbons, additionally CO2 is available on the market.
Fluorinated gas refrigerants are powerful greenhouse gases. Alternatives, such as ammonia or captured carbon dioxide, can replace them over time.
As Freon was phased out, new HVAC systems began using a refrigerant known as Puron® or R-410A, an HFC. More efficient and less harmful to the environment, R-410A has been in use since its introduction in 1996 and is found in most of today's modern HVAC systems.
As a result of modern methods and developments, carbon dioxide is coming back into use as a refrigerant in systems which have efficiencies at least as great as the efficiencies of halocarbon and ammonia systems. Carbon dioxide can be used as a refrigerant in several different ways.
Possible alternatives to R-134a
Attention is increasingly focused on low-GWP refrigerants that are hydrofluoroolefins (HFO). R-1234yf in particular is often seen as a possible alternative to R-134a. The GWP value of R-1234yf is 4, which means it has a very low global warming potential.
Some notable substitutes for R134a [10] in AAC based on the preceding studies are R1234yf [[11], [12], [13], [14]], R1234z (E) [[15], [16], [17]], R152a [[18], [19], [20]], R290 [21,22], R744 [[23], [24], [25]], R430A [26,27], and R444A [28], etc.
A High-Performing Alternative to R-134a
Opteon™ XL10 (R-1234yf) refrigerant is a non-ozone depleting (ODP) hydrofluoroolefin (HFO) option that meets the industry's growing demands for sustainable, safe, and effective solutions.
The commonly used synthetic refrigerants such as R134a, R407C and R410A have a GWP value higher than 2,500. As a result, their production is being phased out.
1,1,1,2-Tetrafluoroethane (R-134a or HFC-134a), one of the main replacements for the formerly widespread R-12. Opteon halogenated olefins now replacing Freons in many applications.
R-22 was a commonly used refrigerant that is being phased out because of its harmful impact on the ozone layer.
1. R-134A. A haloalkane refrigerant with thermodynamic properties, Norflurane is more commonly referred to as R-134A. R-134A is made of a single component and is not blended like most R-12 and R-22 alternatives are.
The first type is R-134a, which replaced the refrigerant commonly known as “freon.” The other is R-1234yf, which is an even more environmentally friendly refrigerant than R-134a. Finding out which refrigerant your vehicle uses is easy with the help of A/C Pro®.
An AC leak will lead to warmer air from your vents over time. In most cases this can be fixed with a proven stop leak additive to seal up any leaks. When it's time for an AC recharge, turn to AutoZone.
R-410A Refrigerant: One of the first R22 alternatives to come out after the Freon ban, R-410A was soon recalled because it, too, has serious effects on the environment. R-454B Refrigerant: This refrigerant was developed to replace R-410A once it was recalled. R-454B is best suited to commercial chillers and heat pumps.
The recent phase-out of R-22 (also known by its popular brand name: Freon®) that occurred January 1, 2020 was years in the making. While we still service HVAC equipment using Freon, most residential HVAC units are now using Puron® or R-410A, a type of hydrocarbon refrigerant without the chlorine.
In 2010, the EPA passed the Clean Air Act, outlawing its use in new devices. As such, new AC systems generally use one of the following types of refrigerants: R-410 (Puron): Most air conditioners produced between 1996 (when scientists invented it) and 2020 use Puron.
R-407C is often used as a replacement for Freon. It has similar thermodynamic properties and is a popular choice for manufacturing new machines.
R-454B is the newest refrigerant, which will gradually replace R-410A, the refrigerant used in current HVAC manufacturing. R-454B is a blend of R-32, a hydrofluorocarbon (HFC), and R-1234yf a hydrofluoroolefin (HFO). R-454B has a lower GWP than previous refrigerants, meaning it has a much lower climate impact.
In chillers, hydrocarbons and ammonia are safe and energy-efficient alternatives to HFCs, both under moderate and high ambient temperature conditions. Heat pumps are also used with hydrocarbons, additionally CO2 is available on the market.
The GWP for R-134a refrigerant is 1,430, making it 1,430 times more harmful than carbon dioxide when released into the atmosphere. There are three refrigerants that can be used to replace R-134a: R-1234yf, R-152a, and R-744.
Introducing R-454B
R-454B is the new refrigerant in 2024. By 2025, the EPA's required phaseout of R-410A will be in full effect, with production, importation, and distribution no longer allowed. HVACR businesses must be evaluating their current choices in coolant and ready to make the jump.
Internal heat exchanger for R1234yf refrigerant (photo: NRF) As you can see from the above description, R134a and R1234yf refrigerants are not completely identical and their substitution will always result in faster degradation of the A/C system and eventually lead to costly repairs.
Why Is R-134A Being Phased Out? When Is the Phaseout Expected to Conclude? Like a lot of '90s relics, R-134A has not aged well. It was known then that 1,1,1,2-tetrafluoroethane could potentially contribute to acid rain and that its ozone layer depletion potential was high.
R32 and R152a have a reduced global warming potential than R134a, which indicates that R32 can be used as substitute for R134a in refrigeration systems.
The chemical stabilities of copper, steel, and aluminum have been tested and confirmed as acceptable for use with Freon™ 134a and lubricants. Acceptable plastics and elastomers have been found for use with existing CFC refrigerants.