In the United States, vehicles produced after 2021 no longer contain R-134A in the air conditioning system. In other parts of the world, including the United States, there are restrictions around using 1,1,1,2-tetrafluoroethane. Specifically, in California, retailers can deny selling customers canned R-134a.
A High-Performing Alternative to R-134a
Opteon™ XL10 (R-1234yf) refrigerant is a non-ozone depleting (ODP) hydrofluoroolefin (HFO) option that meets the industry's growing demands for sustainable, safe, and effective solutions.
The sales restriction is established by EPA regulations (40 CFR Part 82, Subpart F ) under Section 608 of the Clean Air Act. Only EPA-certified technicians are allowed to purchase ozone-depleting substances (ODS) or non-ozone depleting substitutes used as refrigerants, with limited exceptions.
No, you would not replace R134a with R-1234yf for any real reason.
Possible alternatives to R-134a
Attention is increasingly focused on low-GWP refrigerants that are hydrofluoroolefins (HFO). R-1234yf in particular is often seen as a possible alternative to R-134a. The GWP value of R-1234yf is 4, which means it has a very low global warming potential.
Some notable substitutes for R134a [10] in AAC based on the preceding studies are R1234yf [[11], [12], [13], [14]], R1234z (E) [[15], [16], [17]], R152a [[18], [19], [20]], R290 [21,22], R744 [[23], [24], [25]], R430A [26,27], and R444A [28], etc.
The AIM Act is a Federal nationwide rule phasing out the use of global warming materials. As part of that effort, EPA is now banning the use of 134a in aerosol products as of 1/1/2025. There are excepted products that are allowed to use 134a until 1/1/2028.
Still, the answer is an emphatic, “No.” Not only would a retrofit of this type negate the environmental benefits of R-1234yf, but it would also be a violation of Federal Law under Section 203 of the Clean Air Act: “tampering” with a vehicle's emissions control device.
The GWP for R-134a refrigerant is 1,430, making it 1,430 times more harmful than carbon dioxide when released into the atmosphere. There are three refrigerants that can be used to replace R-134a: R-1234yf, R-152a, and R-744.
Refrigerant R513A - Drop-In Alternative for R134a. R513A was developed as a replacement refrigerant for R134a. R513A is a modern, non-flammable refrigerant designed to replace R134a in a wide range of applications. It provides a sustainable solution for both new systems and retrofits.
The commonly used synthetic refrigerants such as R134a, R407C and R410A have a GWP value higher than 2,500. As a result, their production is being phased out. By 2020, around 40% of the total production of synthetic refrigerants have been phased out.
HFC-134a will no longer be allowed in nonroad vehicles as of January 1, 2028. Servicing of existing vehicles using HFC-134a with HFC-134a will not be impacted and will continue to be allowed.
No, the compressor will fail. These two refrigerants have very different properties. One of R22 and R134a is high pressure and the other is low pressure. They don't mix chemically and don't have the same boiling point, leading to inefficiencies and eventual compressor failure.
The mixing of R-134a with R-1234yf will change refrigerant pressure and may result in evaporator freeze-up on pressure control systems, reducing system airflow.
R1234yf was chosen to replace R134a in all new cars by 2021. Some manufacturers have already made the switch, or the switch is in progress. In fact, as of 2018, 70% of new Kia cars already come equipped with R1234yf!
According to its manufacturer, Chemours, use of R-1234yf has grown so much since the refrigerant replaced the long-established R-134a that it's now used in 95% of new cars sold in the U.S. An estimated 220 million cars on global roads are also using it.
If you're looking for a low global warming potential (GWP) alternative alternative, consider Opteon™ XP10 (R-513A)—a new generation hydrofluoroolefin (HFO) refrigerant replacement for R-134a in stationary equipment.
The chemical stabilities of copper, steel, and aluminum have been tested and confirmed as acceptable for use with Freon™ 134a and lubricants. Acceptable plastics and elastomers have been found for use with existing CFC refrigerants.
The test results conclude that the blend R134a/R32 at a mass fraction of 85/15 can be a drop-in replacement for R134a refrigerant.
The Intergovernmental Panel on Climate Change has since added R-134A to its list of greenhouse gases, declaring definitively that this refrigerant is a poor choice for the future of the planet and its inhabitants.
If you are purchasing less than 2 pounds of either R-134a or R-1234yf, you are not required to have a license to purchase either refrigerant. However, if you are working with 10- and 25-pound single-use recyclable cylinders you will need Section 608 Technician Certification.
The different types of refrigerants are not meant to be mixed. The refrigerant charge must be optimized by using the refrigerant's respective pressure-temperature chart.
The banning of R134a, along with 27 other refrigerants, in new domestic refrigerators and freezers from January 1, 2021, is expected to open the way for the use of hydrocarbon refrigerants.
Internal heat exchanger for R1234yf refrigerant (photo: NRF) As you can see from the above description, R134a and R1234yf refrigerants are not completely identical and their substitution will always result in faster degradation of the A/C system and eventually lead to costly repairs.
R-22 (Chlorodifluoromethane), also known as R22 Freon or HCFC-22 Freon, was a common refrigerant for HVAC systems. It is now a banned refrigerant that is illegal to import or manufacture.